In this work, carbon nanofibers were prepared by the heat treatment of polyacrylonitrile pan nanofibers obtained from the electrospinning. Carbon nanofibers prepared from electrospun polyimide. Polyvinyl alcoholcarbon nanotube cnt composite nanofibers were processed by both conventional and needleless electrospinning method. Two polymer solutions of polyacrylonitrile pan, polyvinyl pyrrolidone pvp, and ni ch3cooh2 ni oac2 were used as cni composite nanofiber precursors. Coal liquefaction residues based carbon nanofibers film prepared by electrospinning. Control of physical properties of carbon nanofibers. S1electronic supplementary information highquality janus nanofibers prepared using threefluid fluid electrospinning dengguang yu,a, jiaojiao li,a man zhang,a and gareth r. With zeinibuprofen ibu codissolving solution and n, ndimethylformamide as. Due to the rapid progress in the electrospinning fieldand the limited time for the authors to write the book, some omissions may have occurred. The use of electrospun nanofibers in drug delivery has increased rapidly over recent years due to their valuable properties, which include a large surface area, high porosity, small pore size, superior mechanical properties, and ease of surface modification. All of the electrospinning processes were carried out at 30 c. Raman characterization of carbon nanofibers prepared using electrospinning. Behavior of toluene adsorption on activated carbon nanofibers.
The effects of atmosphere and calcined temperature on photocatalytic activity of tio2 nanofibers prepared by electrospinning, nanoscale research letters, 20, pp. Coal based nanofibers were prepared by electrospinning a mixture of polyacrylonitrile and acid treated coal. Synthesis and characterization of multiwalled cntpan. Yeo micronanophysics research laboratory, department of mechanical engineering, monash university, clayton, vic 3800, australia correspondence leslie. It was observed that the surface of nanofibers without carbon nanospheres was smooth figure 3a while the surface of nanofibers with carbon nanospheres was lumpy at places where the nanospheres were present figure 3c. Coal based activated carbon nanofibers prepared by electrospinning. Adsorption of benzene and ethanol on activated carbon. Despite its larger diameter, ptio 2 nanofibers have larger specific surface area 33 m 2 g than tio 2 nanofibers 9 m 2 g.
A powerful method of synthesising nanofibers comprising these polymer composites is electrospinning, which utilises an applied electric stress to draw out a. The effects of acid treatment on raw coal were studied to explain the enhanced solubility in various solvents. In this process, the as spun nanofibers were stabilized in oxygen atmosphere for a greater stability to sustain at higher temperature. Sintering temperature has an important influence on the performance of the obtained composites. Coal based activated carbon nanofibers prepared by. The effects of acid treatment on raw coal were studied to explain the enhanced solubility in various sol. The asprepared nanofibers were carbonized under argon and washed with acid to obtain porous carbon nanofibers.
Among the polymeric precursors used to manufacture carbon nanofibers through the electrospinning process may be considered the polyacrylonitrile pan, because it present a high carbon yield in the carbonization heat treatment and simple preparation process 6, 18. In this study, undoped and 1, 2,3, 4, and 5 wt % agdoped tio 2 nanofibers have been fabricated by the electrospinning method applying 20 kv voltages at 8 cm height with a flow rate 0. Coalbased carbon nanofibers prepared by electrospinning. The morphology and microstructure of cnfs were characterized by scanning electron microscopy sem and transmission electron microscopy tem. Carbon precursors, pore structure control, improvement in electrical conductivity,and metal loading into carbon.
Novel highly conductive ferroferric oxideporous carbon nanofiber composites prepared by electrospinning as anode materials for high. Pdf coal based nanofibers were prepared by electrospinning a mixture of polyacrylonitrile and acid treated coal. Apr 12, 2019 the article summarizes the scientific progress that has occurred in the past several years in regard to the preparation of carbon nanofibers from lignin as a lowcost environmentallyfriendly raw material using electrospinning. Chapter 10 introduces methods to prepare carbon, inorganic, and metal nanofibers based on electrospinning. Edlc aapplication of carbon nanofiberscarbon nanotubes. Dec 15, 2010 zinc acetatepolyacrylonitrile nanofibers were prepared by an electrospinning method. Hollow activated carbon nanofibers prepared by electrospinning as counter electrodes for dyesensitized solar cells. Electrospun polyimide pi nanofibers are of particular interest for a variety of applications due to their. Singlewalled carbon nanotube swnt reinforced polymer composite membranes have been fabricated using the electrospinning technique. Leemwcntmesoporous carbon nanofibers composites prepared by electrospinning and silica template as counter electrodes for dyesensitized solar cells journal of photochemistry and photobiology a, 246 2012, p. Drug delivery applications of coresheath nanofibers. The acnfs were characterized by scanning electron microscope, xray photoelectron spectroscopy and nitrogen adsorption at 77 k. The pan nanofibers were produced from 9 wt% pan solution by electrospinning technique. Drugloaded zein nanofibers prepared using a modified.
Carbon nanofibers prepared via electrospinning, advanced. After electrospinning, the as spun nanofibers were stabilized and carbonized to obtain the carbon nanofibers. Novel highly conductive ferroferric oxideporous carbon. For the investigation of surface morphology scanning electron. Coal based activated carbon fibers were further obtained by carbonization and steam activation. Adsorption of toluene on carbon nanofibers prepared by. For a more environmentally friendly method of obtaining carbon fibers using electrospinning, ethanol basedlignin may be used. Due to the rapid progress in the electrospinning fieldand the limited. Carbon nanofibers cnfs derived from polyacrylonitrile pan have not yet demonstrated.
Control of physical properties of carbon nanofibers obtained from coaxial electrospinning of pmma and pan with adjustable innerouter nozzleends navaporn kaerkitcha1, surawut chuangchote2,3 and takashi sagawa1 abstract hollow carbon nanofibers hcnfs were prepared by electrospinning method with several coaxial nozzles, in which. Garciamateos et al 2018 prepared an ethanol solution with 40 wt% alcell lignin. Coalbased carbon nanofibers prepared byelectrospinning. Preparation of carbon nanofibers from polyacrylonitrile. Feb 20, 2007 electrospinning carbon nanotube polymer composite nanofibers leslie y.
Coalbased supercapacitor electrodes were further obtained by carbonization and activation. Drug delivery applications of coresheath nanofibers prepared. Carbon nanofibers prepared via electrospinning inagaki 2012. The present invention relates to carbon nanofibers, and more particularly, to a method capable of preparing metal oxidecontaining porous carbon nanofibers having a high specific surface area by changing the composition of a spinning solution, which is used in a process of preparing carbon nanofiber by electrospinning, and to metal oxidecontaining porous carbon nanofibers prepared by the. Control of physical properties of carbon nanofibers obtained. Therefore, because of their unique properties, the cnfs are interesting materials for. Uniform and thin polyaniline carbon nanofiber panicnf hybrid nanofibers has been prepared using electrospinning method. Jun 19, 20 novel electrical conductive carbon nanofibers were prepared by a combination of electrospinning and ionbeam irradiation techniques. Superior electrochemical properties of nanofibers composed. The preparation strategy is expected to be applicable to the preparation of other transition metal oxide materials as superior anode materials for lithiumion batteries. Electrospinning has emerged as one of the potential techniques for producing nanofibers.
Ultrafine fibers were electrospun from polyacrylonitrile pann,ndimethyl formamide dmf solution as a precursor of carbon nanofibers. Figure 3 shows sem images of tio 2 nanofibers and ptio 2 nanofibers before and after calcination. We do apologize about this, and, if the reader findsany omis. Preparation of porous carbon nanofibers by electrospinning. The unique and exceptional physical properties of carbon nanotubes have inspired their use as a filler within a polymeric matrix to produce carbon nanotube polymer composites with enhanced mechanical, thermal and electrical properties. Preparation and characterization of sno2 nanofibers via. Abstract electrospun polyimide pi nanofibers are of particular interest for a variety of applications due to their extraordinary thermal and chemical stability. Ultrafine polyacrylonitrile pan fibers, as a precursor of carbon nanofibers, with diameters in the range of 220760 nm were obtained by electrospinning of pan solution using n,ndimethyl formamide dmf as solvent. The antibacterial effect of these fabricated nanofibers has been determined. Mar 15, 20 carbon nanofibers prepared via electrospinning inagaki, michio. Activated carbon nanofibers acnfs were prepared by electrospinning polyacrylonitrile solutions, and subsequent steam activation process. Facile preparation of nitrogenenriched hierarchical.
Pdf coal based activated carbon nanofibers prepared by. This study investigated the preparation of drugloaded fibers using a modified coaxial electrospinning process, in which only unspinnable solvent was used as sheath fluid. Carbon nanofibers cnfs have attracted considerable attention in recent years because they have superior mechanical strength and excellent electronic properties 1, 2 due to their unique structures, which are low grain boundary, 1d structure with high alignment and high surface area to volume ratio. Facile preparation of nitrogenenriched hierarchical porous. The porous structure within the ptio 2 nanofibers was further confirmed by the n 2 physisorption experiments. Porous carbon nanofibers prepared by the unique calcination process improved the conductivity of composites and provided free space for migration of lithium ions. Most recent developments in electrospun magnetic nanofibers.
Electrospinning carbon nanotube polymer composite nanofibers. By employing the electrospinning technique and subsequent carbonization processes, porous carbon nickle cni composite nanofibers with diameters of 100200 nm were successfully prepared. Viscosity of the solutions was examined using a rotary viscometer, ndj1 type, at 25 c. Carbon nanofibers prepared via electrospinning inagaki, michio.
Read adsorption of toluene on carbon nanofibers prepared by electrospinning, science of the total environment on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Although one of the applications of electrospun carbon nanofibers is the support for catalysts and electrochemi cally active materials, loading. Production of magnetic nanofibers electrospinning technology the electrospinning technology can be used to prepare nanofibers or nanofiber mats from polymer solutions or melts, possibly including ceramics, metallic nanoparticles, carbon nanotubes, and so on, in addition. Raman characterization of carbon nanofibers prepared using. As shown in figure 4, the pores volume of ptio 2 nanofibers was larger than that of nonporous tio 2 nanofibers. It presents an overview of using lignin, electrospinning, and carbonization to convert lignin to carbon nanofibers. Preparation and characterization of porous carbonnickle. Cdoped tio2 nanofibers were prepared by electrospinning successfully. The results indicate that cnfs exhibited small diameter and rough. Graphitized porous carbon nanofibers prepared by electrospinning as anode materials for lithium ion batteries shoupu zhu, jing sun, tian wu, xun su, haiming su, shanshan qu, yongjuan xie, ming chen and guowang diao college of chemistry and chemical engineering, yangzhou university, yangzhou 225002, p. The article summarizes the scientific progress that has occurred in the past several years in regard to the preparation of carbon nanofibers from lignin as a lowcost environmentallyfriendly raw material using electrospinning. May 25, 2017 the transverse moduli of clignin derived carbon fibers found to be better than kraft and commercial carbon fibers.
Four types of polymer nanofibers, including polyimides 6fda. Carbon nanofibers containing agtio 2 composites as a preliminary stage for cdi technology. Carbon nanofibers prepared via electrospinning inagaki. The use of large amounts of environmentally unfriendly, toxic, and flammable organic solvents in electrospinning of polymers puts demand on the development of new methods and formulations for making water stable hydrophobic nanofibers from watersoluble precursor solution.
When increasing the temperature, the pan crystal structure was almost completely destroyed and a. Nitrogenenriched hierarchical porous carbon nanofibers hpcnfs with superior capacitance and outstanding mechanical strength are facilely fabricated by electrospinning of polyacrylonitrilemagnesium acetate panmgoac 2 precursor, preoxidation and carbonization of composite nanofibers, which use pan as carbon source and mgoac 2 as precursor of mgo template. Coalbased carbon nanofibers with uniform diameters were prepared by means of electrospinning with oxidized coal, polyacrylonitrilepan and n, ndimethylformamide dmf. Coal liquefaction residues based carbon nanofibers film. In addition, the structure of the prepared carbon nanofibers was.
Uniform and thin polyanilinecarbon nanofiber panicnf hybrid nanofibers has been prepared using electrospinning method. The electrospinning is carried out by applying a dc voltage to the tip of a syringe and maintaining the tip to collector distance tcd, i. Highquality janus nanofibers prepared using threefluid. Carbon nanofibers prepared via electrospinning wiley online. Three polymer solutions with different components were examined for synthesis of panicnf electrospun nanofibers. Mno carbon hybrid nanofibers are fabricated via an electrospinning method.
Activated carbon nanofibers were prepared with polymer blends that consisted of polyacrylonitrile pan and cellulose acetate ca, by electrospinning and subsequent thermal treatment. The adsorption equilibrium data for benzene and ethanol were obtained by using static vapor adsorption system. Preparation of carbon nanofibers by the combination of. Mnocarbon fibers prepared by an electrospinning method.
Preparation and surface structures of carbon nanofibers produced. Polyimide nanofibers by green electrospinning via aqueous. Coalbased carbon nanofibers prepared byelectrospinning for. Carbon nanofibers reinforced 3d porous carbon polyhedra network ecnfpcp was prepared through electrospinning and subsequent thermal treatment. Abstract in this work, polyacrylonitrile pan and carbon nanofibers with controllable nanoporous structures were successfully prepared via electrospinning technique. The effects of atmosphere and calcined temperature on. Pi nanofibers from waterbased precursor by green electrospinning are prepared and applied for air and high temperature filtrations. Pdf raman characterization of carbon nanofibers prepared. Edlc aapplication of carbon nanofiberscarbon nanotubes electrode prepared by electrospinning chan kim and young hee lee bk21 physics division, center for nanotubes and nanostructured composites cnnc, sungkyunkwan university, suwon, kyunggido 440746, korea the electrospinning method 1 was introduced to prepare nanostructured composites of pan. Kim c, yang kselectrochemical properties of carbon nanofiber web as an electrode for supercapacitor prepared by electrospinning. Edlc aapplication of carbon nanofibers carbon nanotubes electrode prepared by electrospinning chan kim and young hee lee bk21 physics division, center for nanotubes and nanostructured composites cnnc, sungkyunkwan university, suwon, kyunggido 440746, korea the electrospinning method 1 was introduced to prepare nanostructured composites of pan. The effects of solution concentration, applied voltage and flow rate on preparation and morphologies of electrospun pan fibers were investigated.
Apr 15, 2008 read adsorption of toluene on carbon nanofibers prepared by electrospinning, science of the total environment on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Tem observations revealed incorporation of small swnt bundles oriented parallel to the nanofiber axis. Carbon nanofibers containing agtio2 composites as a. Electrospinning of polymeric nanofibers for tissue. Hollow activated carbon nanofibers prepared by electrospinning as counter electrodes for dyesensitized solar cells author links open overlay panel seokhwan park a b c hongryun jung a wanjin lee a b c. The as prepared nanofibers were carbonized under argon and washed with acid to obtain porous carbon nanofibers. Using a furnace, the pan nanofiber was converted into carbon nanofiber. Phenolic resinbased carbon thin fibers prepared by. Material synthesized under optimum temperature can exhibit ideal fiber appearance with mno particles embedded into it. Carbon nanofibers 6667 68 have been prepared through the electrospinning of pan, followed by subsequent stabilization and carbonization. Electrospun carbon nanofibers reinforced 3d porous carbon. The surface and bulk elemental compositions were analyzed by energydispersive xray spectroscopy and xray photoelectron spectroscopy, respectively. Bromelainloaded chitosan nanofibers prepared by electrospinning method for burn wound healing in animal models life sciences, vol.
Morphology of the nanofibers for varying concentration and applied voltage was investigated by field emission scanning electron microscopy fesem. Novel electrical conductive carbon nanofibers were prepared by a combination of electrospinning and ionbeam irradiation techniques. Electrospinning preparation and photocatalytic activity of. Behavior of toluene adsorption on activated carbon. Frontiers ligninbased electrospun carbon nanofibers. Electrospinning has attracted attention of researchers since it. Carbon nanofibers obtained from electrospinning process. Characterization and application of zeolitic imidazolate. The surface morphology and microstructure of the porous carbon nanofibers were examined by scanning electron microscopy and xray diffraction.
Abstract carbon nanofibers prepared via electrospinning and following carbonization are summarized by focusing on the structure and. Different amounts of carbon were added into the nanofibers by using chitosan, aiming to shift the wave length that is required to. Pdf electrical conductivity of panbased carbon nanofibers. Pdf morphological study of hybrid nanofibers based on. Drugloaded zein nanofibers prepared using a modified coaxial. Coal liquefaction residues based carbon fibers film can be successfully obtained by electrospining and exhibits excellent rate performance for supercapacitor. An effective approach to coal waste management xiao li cas key laboratory of carbon materials, institute of coal chemistry, chinese academy of sciences, taoyuan south road, 030001 taiyuan, china. Coalbased carbon nanofibers with uniform diameters were prepared by means of electrospinning with oxidized coal, polyacrylonitrilepan and n,ndimethylformamidedmf. Polyacrylonitrile and carbon nanofibers with controllable. Preparation of singlewalled carbon nanotube reinforced. Recently, carbon nanofibers prepared using electrospinning and subsequent carbonization have been utilized as highperformance anodes for. Investigation of antibacterial properties of ag doped tio2. Lowcost and highperformance electrospun carbon nanofiber. The antibacterial properties of undoped and doped agtio 2 nanofibers were tested on staphylococcus aureus bacteria.
The work was divided into two parts, development of nanofibers and composite nanofiber. The effect of the processing parameters on the possibility of manufacturing was investigated. Zinc acetatepolyacrylonitrile nanofibers were prepared by an electrospinning method. Nanofibers composed of hollow cofe 2 o 4 nanospheres covered with onion.